Some not-so-pericyclic organometallic mechanisms...
Banjare, S. K.; Kumar, S.; Afreen S.; Kong, W.-K.; Guo, W.; Nanda, T.; Adhikari, G. K. D.; Preeyanka, N.; Tantillo, D. J.; Ravikumar, P. C. J. Org. Chem. 2024, 89, 9187-9197: "Cobalt-Catalyzed Deacylative Ipso-C-C Bond Functionalization: An Approach Towards Indole-Acyloins and Its Photophysical Studies"
Hu, M.; Ding, H.; Desnoo, W.; Tantillo, D. J.; Nairoukh, Z. Angew. Chem. Int. Ed. 2023, 62, e202315108: "The Construction of Highly Substituted Piperidines via Dearomative Functionalization Reaction"
Jha, N.; Guo, W.; Kong, W.-Y.; Tantillo, D. J.; Kapur, M. Chem. Eur. J. 2023, 29, e2023015: "Regiocontrol via Electronics: Insights into a Ru-catalyzed, Cu-mediated Site-selective Alkylation of Isoquinolones via a C–C Bond Activation of Cyclopropanols"
Fernandez, G. E.; Maiti, D.; Tantillo, D. J. Chem. Eur. J. 2023, e202300124: "Mechanism and Origins of Site-selectivity of Template-Directed C-H Insertion of Quinolines," invited for special issue on "Mechanisms and Selectivities of Organic Reactions" in honor of Prof. Kendall N. Houk’s 80th birthday.
Nagtilak, P. J.; Mane, M. V.; Prasad, P.; Cavallo, L.; Tantillo, D. J.; Kapur, M. Chem. Eur. J. 2023, 29, e202203055: "Merging Rh-catalyzed C-H Functionalization and Cascade Cyclization to Enable Propargylic Alcohols as Three-Carbon Synthons"
Ragan, A. N.; Kraemer, Y.; Kong, W.-Y.; Prasad, S.; Tantillo, D. J.; Pitts, C. R. Angew. Chem. Int. Ed. 2022, 61, e202208046: "Evidence for C–F Bond Formation through Formal Reductive Elimination from Tellurium(VI)'"
Nanda, T.; Banjare, S. K.; Kong, W.-K.; Guo, W.; Biswal, P.; Gupta, L.; Linda, A.; Pati, B. V.; Mohanty, S. R.; Tantillo, D. J.; Ravikumar, P. C. ACS Catal. 2022, 12, 11651-11659: "Breaking The Monotony: Cobalt and Maleimide as an Entrant to the Olefin Mediated ortho C-H Functionalization"
RETRACTED: Prasad, S.; Tantillo, D. J. Organometallics 2022, 41, 937-947: "Roads Not Taken: Mechanism and Origins of Regio- and Chemoselectivity of Directed Co(III)-catalyzed Alkenylation of N-Pyridyl 2-Pyridone"
Van Hoveln, R.; Hudson, B. M.; Wedler, H. B.; Bates, D. M.; Le Gros, G.; Tantillo, D. J.; Schomaker, J. M. J. Am. Chem. Soc. 2015, 137, 5346-5354: "Mechanistic Studies of Copper(I)-Catalyzed 1,3-Halogen Migration"
